Tetragonal synonyms

When precipitated from solutions it forms red tetragonal crystals, which, on careful heating, give a yellow rhombic form, also obtained by crystallization from the fused substance, or by sublimation.

The density and specific heat of the tetragonal form are greater than those of the yellow.

Ammonium iodide assumes cubic forms with perfect cubic cleavage; tetramethyl ammonium iodide is tetragonal with perfect cleavages parallel to {100} and {o01} - a difference due to the lengthening of the a axes; tetraethyl ammonium iodide also assumes tetragonal forms, but does not exhibit the cleavage of the tetramethyl compound; while tetrapropyl ammonium iodide crystallizes in rhombic form.

The metal is dimorphous: by cooling molten tin at ordinary air temperature tetragonal crystals are obtained, while by cooling at a temperature just below the melting point rhombic forms are produced, When exposed for a sufficient time to very low temperatures (to - 39° C. for 14 hours), tin becomes so brittle that it falls into a grey powder, termed the grey modification, under a pestle; it indeed sometimes crumbles into powder spontaneously.

It loses four molecules of water of crystallization when heated to 100° C. and becomes anhydrous at about 300° C. The hexahydrate is dimorphous, a tetragonal form being obtained by crystallization of a solution of the heptahydrate between 20° and 30° C., and a monoclinic form between 50° and 70° C. Nickel sulphate combines with many metallic sulphates to form double salts, and also forms addition compounds with ammonia aniline and hydroxylamine.