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Boron fluoride BF 3 was first prepared in 1808 by Gay Lussac and L.
The researches of Liebig (1823), Liebig and Gay-Lussac (1824), and of Liebig again in 1838 showed the acid to be isomeric with cyanic acid, and probably (Hcno) 2, since it gave mixed and acid salts.
Gay-Lussac in 181q, is usually obtained in the form of its barium salt by suspending freshly precipitated hydrated manganese dioxide in water and passing sulphur dioxide into the mixture until all is dissolved; the barium salt is then precipitated by the careful addition of barium hydroxide.
Three years later, at an unusually early age, he was elected a member of the Academy of Sciences, and in 1804 he accompanied Gay Lussac on the first balloon ascent undertaken for scientific purposes.
The discovery of boron by Gay Lussac and Davy in 1809 led Berzelius to investigate silica (silex).